全文获取类型
收费全文 | 6104篇 |
免费 | 696篇 |
国内免费 | 579篇 |
专业分类
化学 | 3712篇 |
晶体学 | 28篇 |
力学 | 872篇 |
综合类 | 56篇 |
数学 | 1138篇 |
物理学 | 1573篇 |
出版年
2023年 | 42篇 |
2022年 | 57篇 |
2021年 | 162篇 |
2020年 | 189篇 |
2019年 | 178篇 |
2018年 | 193篇 |
2017年 | 236篇 |
2016年 | 237篇 |
2015年 | 236篇 |
2014年 | 296篇 |
2013年 | 632篇 |
2012年 | 336篇 |
2011年 | 357篇 |
2010年 | 284篇 |
2009年 | 311篇 |
2008年 | 339篇 |
2007年 | 336篇 |
2006年 | 318篇 |
2005年 | 302篇 |
2004年 | 264篇 |
2003年 | 279篇 |
2002年 | 218篇 |
2001年 | 205篇 |
2000年 | 190篇 |
1999年 | 147篇 |
1998年 | 189篇 |
1997年 | 133篇 |
1996年 | 88篇 |
1995年 | 86篇 |
1994年 | 74篇 |
1993年 | 66篇 |
1992年 | 57篇 |
1991年 | 53篇 |
1990年 | 59篇 |
1989年 | 30篇 |
1988年 | 23篇 |
1987年 | 26篇 |
1986年 | 19篇 |
1985年 | 26篇 |
1984年 | 12篇 |
1983年 | 6篇 |
1982年 | 20篇 |
1981年 | 12篇 |
1980年 | 10篇 |
1979年 | 9篇 |
1978年 | 6篇 |
1977年 | 8篇 |
1976年 | 7篇 |
1974年 | 3篇 |
1972年 | 7篇 |
排序方式: 共有7379条查询结果,搜索用时 31 毫秒
31.
Several 2- and 4-alkylcyclohexadienones were prepared and shown to accept electrons to produce ketyl radical anions that dissociated rapidly at room temperature to release carbon-centered radicals and an aromatic phenoxide type anion. In the PET process with benzyl-substituted cyclohexadienones, initiated with triethylamine, the benzyl radicals dimerised or abstracted an H-atom from solvent. In electrochemical reductions, and in reductions with alkali metals in liquid ammonia, the benzyl radicals were further reduced to anions. 相似文献
32.
A new grid‐free upwind relaxation scheme for simulating inviscid compressible flows is presented in this paper. The non‐linear conservation equations are converted to linear convection equations with non‐linear source terms by using a relaxation system and its interpretation as a discrete Boltzmann equation. A splitting method is used to separate the convection and relaxation parts. Least squares upwinding is used for discretizing the convection equations, thus developing a grid‐free scheme which can operate on any arbitrary distribution of points. The scheme is grid free in the sense that it works on any arbitrary distribution of points and it does not require any topological information like elements, faces, edges, etc. This method is tested on some standard test cases. To explore the power of the grid‐free scheme, solution‐based adaptation of points is done and the results are presented, which demonstrate the efficiency of the new grid‐free scheme. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
33.
朱锡雄 《宁波大学学报(理工版)》1993,(1)
以连续体的各力学守恒定律和熵函数为基础,给出了完备的变形体内参量热力学的表述框架。讨论了将热力学状态参量分划为外参量和内参量的必要性和依据,论证了热力学内参量和非弹性变形的关系以及将各种类型的非弹性应变列为内参量的数学条件。给出了考虑非弹性变形的内参量热力学基本方程,讨论了熵平衡和熵产生的关系方程和行为特性。引入两种定义的变形体自由能函数的表述方程,给出了各相应的状态方程组。 相似文献
34.
James V. Crivello 《Journal of polymer science. Part A, Polymer chemistry》2007,45(18):4331-4340
The irradiation of hybrid photopolymer systems consisting of a free radically polymerizable multifunctional acrylate monomer and a cationically polymerizable epoxide or oxetane monomer was conducted under conditions where only the free radical polymerization takes place. This results in the formation of a free‐standing polyacrylate network film containing quiescent oxonium ions along with the unreacted cyclic ether monomer. The subsequent application of a point source of heat to the film ignites a cationic ring‐opening frontal polymerization that emanates from that site and propagates to all portions of the irradiated sample. This article examines the impact of various molecular structural and experimental parameters on these novel hybrid frontal polymerizations that produce interpenetrating network polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4331–4340, 2007 相似文献
35.
Hong-Nian Li Xiao-Xiong WangWang-Feng Ding 《Journal of Electron Spectroscopy and Related Phenomena》2006
Using X-ray photoemission measurements, we have determined the attenuation length of C 1s photoelectrons in C60 film to be 21.5 Å with the incident photon energy of Mg Kα radiation. The inelastic mean free path calculated with the TPP-2M algorithm coincides fairly well with the experimentally determined attenuation length, indicating the validity of the algorithm to fullerene and fullerides. The inelastic mean free paths for some fullerides, i.e. K3C60, K6C60, Ba4C60, Sm2.75C60 and Sm6C60 are calculated to help the quantitative analyses of the photoemission spectra for these compounds. 相似文献
36.
Roderich Tumulka 《Foundations of Physics》2007,37(2):186-197
In a recent paper Conway and Kochen, Found. Phys. 36, 2006, claim to have established that theories of the Ghirardi-Rimini-Weber
(RW) type, i.e., of spontaneous wave function collapse, cannot be made relativistic. On the other hand, relativistic GRW-type
theories have already been presented, in my recent paper, J. Stat. Phys. 125, 2006, and by Dowker and Henson, J. Stat. Phys.
115, 2004. Here, I elucidate why these are not excluded by the arguments of Conway and Kochen.
相似文献
37.
等腰三角形Mindlin板的自由振动分析 总被引:2,自引:0,他引:2
提出了一种新方法来对基于 Mindlin剪切变形理论的等腰三角形板进行自由振动分析 .此方法采用了一种新的基函数并利用 pb-2 Rayleigh-Ritz边界函数得到了一种新型的 Ritz方法 .这种方法的有效性通过收敛性和对比性分析得到了证实 .数值结果表明此方法相当精确有效 . 相似文献
38.
给出了如下的非线性椭圆方程自由边值问题-Δu=λu+(1+ε)u+p,x∈B Rn,u|Ω=μ,∫Ωnu=-M(1)在C[0,1]中的球对称解的存在性.并得到比上述问题更一般的非线性椭圆方程自由边值问题-Δu=h(u),x∈B Rn,u|Ω=μ,∫Ωun=-M,在C[0,1]中的球对称解的存在性,其中B为Rn中的单位球,p>1,λ>0,μ<0,M>0,ε>0;λ,μ,M,ε均为常数,n为正整数. 相似文献
39.
Piotr Rybka 《Journal of Differential Equations》2002,181(2):340-366
We study the behavior of solutions of the modified Stefan problem in the plane for polygonal interfaces. We are particularly interested in a solution near a singularity of either the loss of a facet or the breaking of a facet. We establish precise regularity results if a facet disappears. We use them to establish the existence of a weak solution with singular data, i.e., when some of the zero-crystalline-curvature facets have zero length. 相似文献
40.